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Bankai is the final and most powerful release form of a Zanpaktou. When achieved, it multiplies the wielder's power by a factor of 5-10. Here are the shinigami who have a confirmed bankai, with the name of their Zanpakutou:

Mayuri Kurotsuchi - Ashisogi Jizō - Konjiki Ashisogi Jizō

Renji Abarai - Zabimaru - Hihiō Zabimaru

Byakuya Kuchiki - Senbonzakura - Senbonzakura Kageyoshi

Kaname Tōsen - Suzumushi - Suzumushi Tsuishiki: Enma Kōrogi

Sajin Komamura - Tenken - Kokujō Tengen Myō'ō

Ichigo Kurosaki - Zangetsu - Tensa Zangetsu

Tōshiro Hitsugaya - Hyōrinmaru - Daiguren Hyōrinmaru

Ikkaku Madarame - Hōzukimaru - Ryūmon Hōzukimaru

Shūsuke Amagai - Raika - Raika Gōen Kaku

Soi Fon - Suzumebachi - Jakuhō Raikōben

Kensei Muguruma - Tachikaze - Tekken Tachikaze

Gin Ichimaru - Shinsō - Kamishini no Yari

Chōjirō Sasakibe - Gonryōmaru - Kōkō Gonryō Rikyū

Genryūsai Shigekuni Yamamoto - Ryūjin Jakka - Zanka no Tachi

Retsu Unohana - Minazuki - Minazuki - (Same name - Different translation)

Rōjurō Otoribashi - Kinshara - Kinshara Butōdan

Renji Abarai - Zabimaru - Sōō Zabimaru

Rukia Kuchiki - Sode no Shirayuki - Hakka no Togame

Shunsui Kyōraku - Katen Kyōkotsu - Katen Kyōkotsu: Karamatsu Shinjū

It has also been assumed that the following shinigami have achieved bankai because of their status in the Thirteen Protection Squads:

Kisuke Urahara, Ukitake Jūshiro, Sōsuke Aizen, Yoruichi Shihōin, Isshin Kurosaki and Shinji Hirako.

It has also been implied that the following characters have attempted to achieve bankai but have yet to:

Yumichika Ayasegawa, Rangiku Matsumoto, Izuru Kira and Shūhei Hisagi.

Hope this helps.

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