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Yes, they are.

Here is a list of the antagonists in the series:

  1. Sousuke Aizen, Kaname Tousen, & Gin Ichimaru.
  2. The Bounts.
  3. The Arrancar / Espada / Hollows.
  4. Kumoi Gyoukaku, Nukui Hanza, Shuusuke Amagai
  5. Muramasa
  6. Kageroza Inaba
  7. Vandenreich

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